Ethanol is most commonly used to
power automobiles, though it may be used to power other vehicles,
such as farm tractors and airplanes
Ethanol fuel is a biofuel alternative to gasoline. It can be
combined with gasoline in any concentration up to pure ethanol
(E100). Anhydrous ethanol, that is, ethanol with at most 1% water,
can be blended with gasoline in varying quantities to reduce
consumption of petroleum fuels and in attempts to reduce air
pollution.
Fuel Additives - E10 & E85
There are three types of gasoline
additives, methyl tert-butyl ether (MTBE), ethanol and ethyl tert-butyl
ether (ETBE). Ethanol is increasingly used as an oxygenate additive
for standard gasoline, as a replacement for methyl t-butyl ether
(MTBE). At a 10% mixture, ethanol reduces the likelihood of engine
knock, by raising the octane rating. The use of 10% ethanol gasoline
is mandated in some cities where the possibility of harmful levels
of auto emissions are possible, especially during the winter months.
Worldwide automotive ethanol capabilities vary widely and most
spark-ignited gasoline style engines will operate well with mixtures
of 10% ethanol (E10) (10% ethanol and 90% gasoline). For E10, the
effect is small (~3%) when compared to conventional gasoline, and
even smaller (1-2%) when compared to oxygenated and reformulated
blends. However, for E85 (85% ethanol), the effect becomes
significant.
E-85 is fuel composed of 85% Ethanol and 15% Gasoline. E-85 has
additional benefits such as burning cleaner than gasoline and having
a higher-octane level resulting in more horsepower. With the recent
rise in gasoline prices, E-85 is price competitive also. Although
most North American gasoline powered vehicles will tolerate up to
10% Ethanol, E-85 compatible engines must be designed and built to
accept this fuel. Flexible Fuel Vehicle (FFV) allows the fuel
injection system to monitor the Ethanol content and adjust the
system automatically. Thereby allowing drivers to fill up with E-85,
regular gasoline or any combination of both. Many automotive
companies have licenced this system and have built cars and trucks,
which are FFV.
FACT: Ethanol-blended fuel keeps your
fuel system clean for optimal performance because it does not leave
gummy deposits.
FACT: With a 113 octane rating, ethanol is the highest performance
fuel on the market and keeps today's high-compression engines
running smoothly.
Graphic Source: FRA (Renewable Fuels Association)
With
the significantly-increasing labor productivity in agriculture
countries, Ethanol fuel has become practical and has been greatly
promoted worldwide. New regulations on gasoline quality and the
additive application have an important impact on production in
conventional refinery plants. Ethanol as the additive has become a trend to reduce the
use of ethers in the production.
MTBE
Methyl t-butyl ether (MTBE) was
used a lot as gasoline additive but is difficult to retrieve from
groundwater and soil contamination. After twenty years of MTBE
(methyl tert-butyl ether)
experience, the United States is now back to ethanol as the
replacement of MTBE because the additive MTBE is currently being
phased out due to ground water contamination..
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ETBE
ETBE was
prepared from ethanol and tert-butyl alcohol on strong acid cation
exchange resin via reactive distillation coupled with pervaporation.
The comparison of several kinds of catalyst on the reactions was
investigated and the reaction kinetics model was established.
Separation of water by the hollow fiber membrane and the reactions
coupled with pervaporation were researched. The comparison of ETBE
yield via reactive distillation with and without pervaporation was
carried out. According to measurement results, ETBE, as a gasoline
blender produced by this methodology was superior to MTBE.